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Molecules 2010, 15(9), 6306-6331; doi:10.3390/molecules15096306

Recent Applications of Polymer Supported Organometallic Catalysts in Organic Synthesis

Organic Chemistry, Department of Chemical and Biological Engineering, Chalmers University of Technology, SE-41296 Göteborg, Sweden
Received: 18 June 2010 / Revised: 18 August 2010 / Accepted: 2 September 2010 / Published: 7 September 2010
(This article belongs to the Special Issue Solid Phase Synthesis)
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Abstract

Recent developments concerning the application of polymer supported organometallic reagents in solid phase synthesis are reviewed, with a special focus on methodology for carbon-carbon formation. Examples of reactions that are covered include the classical Suzuki, Sonogashira and Heck coupings, but also aryl amination, epoxide opening, rearrangements, metathesis and cyclopropanation. Applications in the field of asymmetric synthesis are also discussed.
Keywords: polymer supported; organometallic; solid phase synthesis; cross-coupling; metathesis; allylic substitution; transfer hydrogenation; aryl amination polymer supported; organometallic; solid phase synthesis; cross-coupling; metathesis; allylic substitution; transfer hydrogenation; aryl amination
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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Kann, N. Recent Applications of Polymer Supported Organometallic Catalysts in Organic Synthesis. Molecules 2010, 15, 6306-6331.

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