Molecules 2010, 15(3), 1487-1500; doi:10.3390/molecules15031487
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Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins

Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering and High Technology Research Center, Kansai University, Suita, Osaka 564-8680, Japan
* Authors to whom correspondence should be addressed.
Received: 15 January 2010; in revised form: 2 February 2010 / Accepted: 8 March 2010 / Published: 9 March 2010
(This article belongs to the Special Issue Heck Coupling)
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Abstract: The direct aerobic coupling reaction of arenes with olefins was successfully achieved by the use of Pd(OAc)2/molybdovanadophosphoric acid (HPMoV) as a key catalyst under 1 atm of dioxygen. This catalytic system could be extended to the coupling reaction of various substituted benzenes with olefins such as acrylates, aclrolein, and ethylene through the direct aromatic C-H bond activation.
Keywords: direct coupling; oxidative coupling; arenes; molybdovanadophosphoric acid

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MDPI and ACS Style

Obora, Y.; Ishii, Y. Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins. Molecules 2010, 15, 1487-1500.

AMA Style

Obora Y, Ishii Y. Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins. Molecules. 2010; 15(3):1487-1500.

Chicago/Turabian Style

Obora, Yasushi; Ishii, Yasutaka. 2010. "Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins." Molecules 15, no. 3: 1487-1500.

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