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Molecules 2010, 15(3), 1433-1441; doi:10.3390/molecules15031433
Article

Mild and Efficient Strontium Chloride Hexahydrate-Catalyzed Conversion of Ketones and Aldehydes into Corresponding gem- Dihydroperoxides by Aqueous H2O2

* ,
 and
Faculty of Chemistry, Bu-Ali Sina University, 65178 Hamadan, Iran
* Author to whom correspondence should be addressed.
Received: 15 January 2010 / Revised: 11 February 2010 / Accepted: 1 March 2010 / Published: 8 March 2010
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Abstract

SrCl2·6H2O has been shown to act as an efficient catalyst for the conversion of aldehydes or ketones into the corresponding gem-dihydroperoxides (DHPs) by treatment with aqueous H2O2 (30%) in acetonitrile. The reactions proceed under mild and neutral conditions at room temperature to afford good to excellent yields of product.
Keywords: gem-dihydroperoxide; strontium chloride hexahydrate; ketone; aldehyde; hydrogen peroxide gem-dihydroperoxide; strontium chloride hexahydrate; ketone; aldehyde; hydrogen peroxide
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Azarifar, D.; Khosravi, K.; Soleimanei, F. Mild and Efficient Strontium Chloride Hexahydrate-Catalyzed Conversion of Ketones and Aldehydes into Corresponding gem- Dihydroperoxides by Aqueous H2O2 . Molecules 2010, 15, 1433-1441.

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