Unexplored Nucleophilic Ring Opening of Aziridines†
AbstractThe reactivity of dianions of carboxylic acids towards aziridines has been studied. Although, a similar reactivity to that of enolates from ketones, esters or amides has been observed, the method directly yields g-aminoacids in one step. The method is complementary of previous results of enenediolate reactivity with other electrophiles. A comparative study with the reactivity of this enediolates with epoxides is included.
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Costero, A.M.; Gil, S.; Parra, M.; Rodríguez, P. Unexplored Nucleophilic Ring Opening of Aziridines. Molecules 2010, 15, 9135-9144.
Costero AM, Gil S, Parra M, Rodríguez P. Unexplored Nucleophilic Ring Opening of Aziridines. Molecules. 2010; 15(12):9135-9144.Chicago/Turabian Style
Costero, Ana María; Gil, Salvador; Parra, Margarita; Rodríguez, Pablo. 2010. "Unexplored Nucleophilic Ring Opening of Aziridines." Molecules 15, no. 12: 9135-9144.