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Molecules 2010, 15(11), 7724-7731; doi:10.3390/molecules15117724

The Knoevenagel-Doebner Reaction on 1,2-O-(2,2,2-Trichloroethylidene) Derivatives of D-Gluco- and D-Manno- furanose

1
Chemistry Department, Faculty of Science, Ege University, Bornova, İzmir 35100, Turkey
2
Chemistry Department, Faculty of Arts and Sciences, Celal Bayar University, Campus of Muradiye, Manisa 45030, Turkey
Initial data was presented at the 11th International Electronic Conference on Synthetic Organic Chemistry, ECSOC-11, 1-30 November 2007, paper a007.
*
Author to whom correspondence should be addressed.
Received: 8 October 2010 / Revised: 25 October 2010 / Accepted: 28 October 2010 / Published: 29 October 2010
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Abstract

The synthesis of new α,β-unsaturated furanuronic acid derivatives of α-gluco- (3), β-gluco- (6) and β-manno-chloraloses (9) via a convenient one pot procedure using the Knoevenagel-Doebner reaction approach are described. The dialdofuranose derivatives were reacted with malonic acid under Knoevenagel-Doebner reaction conditions and (E)-α,β-unsaturated furanuronic acid derivatives were obtained.
Keywords: chloralose; trichloroethylidene; dialdofuranose; Knoevenagel-Doebner reaction; sugar chain extension chloralose; trichloroethylidene; dialdofuranose; Knoevenagel-Doebner reaction; sugar chain extension
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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MDPI and ACS Style

Kök, G.; Karayıldırım, T.; Ay, K.; Ay, E. The Knoevenagel-Doebner Reaction on 1,2-O-(2,2,2-Trichloroethylidene) Derivatives of D-Gluco- and D-Manno- furanose. Molecules 2010, 15, 7724-7731.

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