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Molecules 2009, 14(3), 1234-1244; doi:10.3390/molecules14031234
Article

X-ray and Hydrogen-bonding Properties of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol

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Received: 3 November 2008; in revised form: 21 January 2009 / Accepted: 20 February 2009 / Published: 23 March 2009
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Abstract: The solid state structure of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol, C17H13N3O, shows that this Mannich base crystallizes forming intermolecular N···HO hydrogen bonds, rather than intramolecular ones. Factors contributing to this choice of hydrogen-bonding mode are discussed. The compound crystallizes in the monoclinic system, P21/c space group, with lattice constants: a = 11.7934(9) Å, b = 14.3002(14) Å, c = 8.4444(8) Å, β = 106.243(5) deg, V = 1367.3(2) Å3, Z = 4, F(000) = 576, R1 = 6.96%, wR2 = 11.4%.
Keywords: Mannich bases; Benzotriazole; Intra-intermolecular hydrogen bond; 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol; Single crystal X-ray diffraction Mannich bases; Benzotriazole; Intra-intermolecular hydrogen bond; 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol; Single crystal X-ray diffraction
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Rivera, A.; Duarte, Y.; González-Salas, D.; Ríos-Motta, J.; Zaragoza, G. X-ray and Hydrogen-bonding Properties of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol. Molecules 2009, 14, 1234-1244.

AMA Style

Rivera A, Duarte Y, González-Salas D, Ríos-Motta J, Zaragoza G. X-ray and Hydrogen-bonding Properties of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol. Molecules. 2009; 14(3):1234-1244.

Chicago/Turabian Style

Rivera, Augusto; Duarte, Yorley; González-Salas, Diego; Ríos-Motta, Jaime; Zaragoza, Guillermo. 2009. "X-ray and Hydrogen-bonding Properties of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol." Molecules 14, no. 3: 1234-1244.


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