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Molecules 2008, 13(2), 301-318; doi:10.3390/molecules13020301
Article

1,2-Diaryl(3-pyridyl)ethanone Oximes. Intermolecular Hydrogen Bonding Networks Revealed by X-ray Diffraction

1,* , 1, 2, 3, 3 and 2
Received: 30 December 2007; in revised form: 1 February 2008 / Accepted: 4 February 2008 / Published: 7 February 2008
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Abstract: The synthesis of a set of 1-aryl-2-aryl(3-pyridyl)ethanones 1-5 and thecorresponding ketoximes 6-9 is reported. Structural studies of oximes 6, 7 and 9 wereperformed in solution using 1H-NMR and in the solid state by X-ray crystallography,providing evidence of H-bonding networks. The crystal packing was controlled byhomomeric intermolecular oxime···oxime H-bond interactions for 6 and cooperativeoxime···N(pyridyl) and CH/π interactions for 7 and 9.
Keywords: Oximes; ethanones; hydrogen bonds; self-assembly; X-ray diffraction crystalography Oximes; ethanones; hydrogen bonds; self-assembly; X-ray diffraction crystalography
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Alcalde, E.; Mesquida, N.; Alvarez-Rúa, C.; Cuberes, R.; Frigola, J.; García-Granda, S. 1,2-Diaryl(3-pyridyl)ethanone Oximes. Intermolecular Hydrogen Bonding Networks Revealed by X-ray Diffraction. Molecules 2008, 13, 301-318.

AMA Style

Alcalde E, Mesquida N, Alvarez-Rúa C, Cuberes R, Frigola J, García-Granda S. 1,2-Diaryl(3-pyridyl)ethanone Oximes. Intermolecular Hydrogen Bonding Networks Revealed by X-ray Diffraction. Molecules. 2008; 13(2):301-318.

Chicago/Turabian Style

Alcalde, Ermitas; Mesquida, Neus; Alvarez-Rúa, Carmen; Cuberes, Rosa; Frigola, Jordi; García-Granda, Santiago. 2008. "1,2-Diaryl(3-pyridyl)ethanone Oximes. Intermolecular Hydrogen Bonding Networks Revealed by X-ray Diffraction." Molecules 13, no. 2: 301-318.



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