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Molecules 2006, 11(7), 523-527; doi:10.3390/11070523

[Hydroxy(tosyloxy)iodo]benzene Mediated α-Azidation of Ketones

Department of Chemistry, Kurukshetra University, Kurukshetra, Haryana, India
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Received: 20 August 2005 / Revised: 10 March 2006 / Accepted: 12 March 2006 / Published: 14 July 2006
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Abstract

Reaction of various ketones with [hydroxy(tosyloxy)iodo]benzene (HTIB) followed by treatment of the α-tosyloxy ketones thus generated in situ with NaN3 offers a one-pot procedure for the synthesis of α-azido ketones. The HTIB used in this conversion may also be generated in situ by using iodosobenzene in combination with p-toluene- sulphonic acid. View Full-Text
Keywords: Hypervalent iodine; α-azido ketones; [hydroxy(tosyloxy)iodo]benzene; iodosobenzene. Hypervalent iodine; α-azido ketones; [hydroxy(tosyloxy)iodo]benzene; iodosobenzene.
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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MDPI and ACS Style

Prakash, O.; Pannu, K.; Prakash, R.; Batra, A. [Hydroxy(tosyloxy)iodo]benzene Mediated α-Azidation of Ketones. Molecules 2006, 11, 523-527.

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