Molecules 2006, 11(1), 34-42; doi:10.3390/11010034
Article

Criss-cross Cycloadditions on Ketazines Derived from Alicyclic Ketones

Jiri Verner and Milan Potacek* email
Department of Organic Chemistry, Faculty of Science, Masaryk University Brno, Kotlarska 2, 611 37 Brno, Czech Republic
* Author to whom correspondence should be addressed.
Received: 3 August 2004; in revised form: 20 December 2005 / Accepted: 20 December 2005 / Published: 31 January 2006
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Abstract: The reactivity of alicyclic ketazines in criss-cross cycloadditions was investigated. They react with potassium cyanate and ammonium thiocyanate in the presence of acetic acid to form spirocyclic perhydro[1,2,4]triazolo[1,2-a][1,2,4]triazole-1,5-diones and perhydro[1,2,4]triazolo[1,2-a][1,2,4]triazole-1,5-dithiones, respectively, in relatively high yields.
Keywords: Criss-cross cycloaddition; ketazines; cyclohexanone azine; cyclopentanone azine; cycloheptanone azine; substituted perhydro[1; 2; 4]triazolo[1; 2-a][1; 2; 4]triazole-1; 5- diones; substituted perhydro[1; 2; 4]triazolo[1; 2-a][1; 2; 4]triazole-1; 5-dithiones; spiro compounds.

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Cite This Article

MDPI and ACS Style

Verner, J.; Potacek, M. Criss-cross Cycloadditions on Ketazines Derived from Alicyclic Ketones. Molecules 2006, 11, 34-42.

AMA Style

Verner J, Potacek M. Criss-cross Cycloadditions on Ketazines Derived from Alicyclic Ketones. Molecules. 2006; 11(1):34-42.

Chicago/Turabian Style

Verner, Jiri; Potacek, Milan. 2006. "Criss-cross Cycloadditions on Ketazines Derived from Alicyclic Ketones." Molecules 11, no. 1: 34-42.

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