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Molecules 2005, 10(8), 1010-1014; doi:10.3390/10081010
Article

Preparation of an Eight-Membered Sesquiterpene Lactone Resulting from Sequential Gif System GoAggIII and MCPBA Oxidation of ( )-10β,14-Dihydroxy-allo-aromadendrane

1, 2, 1 and 1,*
1 Universidade Federal de Mato Grosso do Sul, Departamento de Química, Brazil 2 Universidade Federal de Mato Grosso do Sul, Departamento de Morfofisiologia, Brazil
* Author to whom correspondence should be addressed.
Received: 8 December 2004 / Accepted: 2 March 2005 / Published: 31 August 2005
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Abstract

Studies aimed at a comparison of chemical, biomimetic (Gif system GoAggIII)and enzymatic (CHMO) transformations of natural ( )-10β,14-dihydroxy-allo-aromadendrane have led to preparation of an eight-member sesquiterpene lactone.
Keywords: (+)-10β; 14-dihydroxy-allo-aromadendrane; (-)-allo-aromandendrone; apo- aromadendrone; eight-member sesquiterpene lactone; GoAggIII; CHMO; MCPBA; Baeyer-Villiger (+)-10β; 14-dihydroxy-allo-aromadendrane; (-)-allo-aromandendrone; apo- aromadendrone; eight-member sesquiterpene lactone; GoAggIII; CHMO; MCPBA; Baeyer-Villiger
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).
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De Bodas, M.; Marques, M.; Beatriz, A.; De Lima, D. Preparation of an Eight-Membered Sesquiterpene Lactone Resulting from Sequential Gif System GoAggIII and MCPBA Oxidation of ( )-10β,14-Dihydroxy-allo-aromadendrane. Molecules 2005, 10, 1010-1014.

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