Preparation of an Eight-Membered Sesquiterpene Lactone Resulting from Sequential Gif System GoAggIII and MCPBA Oxidation of ( )-10β,14-Dihydroxy-allo-aromadendrane

doi:10.3390/10081010

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Molecules 2005, 10(8), 1010-1014; doi:10.3390/10081010

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Preparation of an Eight-Membered Sesquiterpene Lactone Resulting from Sequential Gif System GoAgg^III and MCPBA Oxidation of ( )-10β,14-Dihydroxy-allo-aromadendrane

M. De Bodas¹, M. Marques², A. Beatriz¹ and D. De Lima^1,*

¹ Universidade Federal de Mato Grosso do Sul, Departamento de Química, Brazil ² Universidade Federal de Mato Grosso do Sul, Departamento de Morfofisiologia, Brazil

* Author to whom correspondence should be addressed.

Received: 8 December 2004 / Accepted: 2 March 2005 / Published: 31 August 2005

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Abstract: Studies aimed at a comparison of chemical, biomimetic (Gif system GoAgg^III)and enzymatic (CHMO) transformations of natural ( )-10β,14-dihydroxy-allo-aromadendrane have led to preparation of an eight-member sesquiterpene lactone.

Keywords: (+)-10β; 14-dihydroxy-allo-aromadendrane; (-)-allo-aromandendrone; apo- aromadendrone; eight-member sesquiterpene lactone; GoAggIII; CHMO; MCPBA; Baeyer-Villiger

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MDPI and ACS Style

De Bodas, M.; Marques, M.; Beatriz, A.; De Lima, D. Preparation of an Eight-Membered Sesquiterpene Lactone Resulting from Sequential Gif System GoAgg^III and MCPBA Oxidation of ( )-10β,14-Dihydroxy-allo-aromadendrane. Molecules 2005, 10, 1010-1014.

AMA Style

De Bodas M, Marques M, Beatriz A, De Lima D. Preparation of an Eight-Membered Sesquiterpene Lactone Resulting from Sequential Gif System GoAgg^III and MCPBA Oxidation of ( )-10β,14-Dihydroxy-allo-aromadendrane. Molecules. 2005; 10(8):1010-1014.

Chicago/Turabian Style

De Bodas, M.; Marques, M.; Beatriz, A.; De Lima, D. 2005. "Preparation of an Eight-Membered Sesquiterpene Lactone Resulting from Sequential Gif System GoAgg^III and MCPBA Oxidation of ( )-10β,14-Dihydroxy-allo-aromadendrane." Molecules 10, no. 8: 1010-1014.

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