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Molecules 2005, 10(1), 244-250; doi:10.3390/10010244
Article

Substrate Dependence in Aqueous Diels-Alder Reactions of Cyclohexadiene Derivatives with 1,4-Benzoquinone

 and *
Received: 10 May 2004; in revised form: 25 November 2004 / Accepted: 25 November 2004 / Published: 31 January 2005
(This article belongs to the Special Issue Hypervalent Iodine)
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Abstract: A reactivity difference based on the position of substituents on cyclohexa-1,3- diene was observed for the title reaction. The effect of water as solvent was more distinct for 1-methyl-4-isopropylcyclohexa-1,3-diene than for 2-methyl-5-isopropylcyclohexa- 1,3-diene or non-substituted cyclohexa-1,3-diene. The effect of NaCl (salting-out) and guanidium chloride (salting-in) was also large for 1-methyl-4-isopropylcyclohexa-1,3- diene.
Keywords: Diels-Alder reaction; aqueous; cyclohexadiene; substrate dependence Diels-Alder reaction; aqueous; cyclohexadiene; substrate dependence
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Sunakawa, T.; Kuroda, C. Substrate Dependence in Aqueous Diels-Alder Reactions of Cyclohexadiene Derivatives with 1,4-Benzoquinone. Molecules 2005, 10, 244-250.

AMA Style

Sunakawa T, Kuroda C. Substrate Dependence in Aqueous Diels-Alder Reactions of Cyclohexadiene Derivatives with 1,4-Benzoquinone. Molecules. 2005; 10(1):244-250.

Chicago/Turabian Style

Sunakawa, Takeshi; Kuroda, Chiaki. 2005. "Substrate Dependence in Aqueous Diels-Alder Reactions of Cyclohexadiene Derivatives with 1,4-Benzoquinone." Molecules 10, no. 1: 244-250.



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