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Molecules 2005, 10(1), 238-243; doi:10.3390/10010238
Article

Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines

, *  and
State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China
* Author to whom correspondence should be addressed.
Received: 17 August 2004 / Accepted: 15 September 2004 / Published: 31 January 2005
(This article belongs to the Special Issue Hypervalent Iodine)
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Abstract

The palladium-catalyzed cross-coupling carbonyl insertion reaction between 3,7-bis(N,N-dimethylamino)-10H-dibenz[b,e]iodinium iodide (1) and alcohols or amines 2 is described. Some new amides and esters 3 containing an active iodo functional group have been prepared in 65-91% yields.
Keywords: Cross-coupling; hypervalent iodoheterocycle; carbonyl insertion; amides; esters Cross-coupling; hypervalent iodoheterocycle; carbonyl insertion; amides; esters
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Luo, S.-J.; Ma, Y.-X.; Liang, Y.-M. Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines. Molecules 2005, 10, 238-243.

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