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Molecules 2005, 10(1), 238-243; doi:10.3390/10010238
Article

Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines

, *  and
State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China
* Author to whom correspondence should be addressed.
Received: 17 August 2004 / Accepted: 15 September 2004 / Published: 31 January 2005
(This article belongs to the Special Issue Hypervalent Iodine)
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Abstract

The palladium-catalyzed cross-coupling carbonyl insertion reaction between 3,7-bis(N,N-dimethylamino)-10H-dibenz[b,e]iodinium iodide (1) and alcohols or amines 2 is described. Some new amides and esters 3 containing an active iodo functional group have been prepared in 65-91% yields.
Keywords: Cross-coupling; hypervalent iodoheterocycle; carbonyl insertion; amides; esters Cross-coupling; hypervalent iodoheterocycle; carbonyl insertion; amides; esters
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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Luo, S.-J.; Ma, Y.-X.; Liang, Y.-M. Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines. Molecules 2005, 10, 238-243.

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