Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines

doi:10.3390/10010238

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Molecules 2005, 10(1), 238-243; doi:10.3390/10010238

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Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines

Shengj-Jun Luo, Yong-Xiang Ma* and Yong-Min Liang

State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China

* Author to whom correspondence should be addressed.

Received: 17 August 2004 / Accepted: 15 September 2004 / Published: 31 January 2005

(This article belongs to the Special Issue Hypervalent Iodine)

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Abstract: The palladium-catalyzed cross-coupling carbonyl insertion reaction between 3,7-bis(N,N-dimethylamino)-10H-dibenz[b,e]iodinium iodide (1) and alcohols or amines 2 is described. Some new amides and esters 3 containing an active iodo functional group have been prepared in 65-91% yields.

Keywords: Cross-coupling; hypervalent iodoheterocycle; carbonyl insertion; amides; esters

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MDPI and ACS Style

Luo, S.-J.; Ma, Y.-X.; Liang, Y.-M. Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines. Molecules 2005, 10, 238-243.

AMA Style

Luo S-J, Ma Y-X, Liang Y-M. Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines. Molecules. 2005; 10(1):238-243.

Chicago/Turabian Style

Luo, Shengj-Jun; Ma, Yong-Xiang; Liang, Yong-Min. 2005. "Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines." Molecules 10, no. 1: 238-243.

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